Reaction Summary

Reagents

  • Concentrated acidified potassium manganate(VII), /

Conditions

  • Hot, heat under reflux

Catalyst

  • None

Chemical Equation

Equation

By-Products

  • Depends on the other alkene carbon: ➔ ; ➔

Observations

Observations

  • Purple solution turns colourless ( ➔ )

⚠️ 9701 Exam Notes / Pitfalls

Warning

  • Oxidative cleavage — the C=C breaks completely.
  • A ketone only forms from an alkene carbon with two alkyl groups and no H ().
  • Exams use this backwards: identify the products to deduce the position of C=C in the original alkene.
  • Contrast with cold, dilute acidified ➔ diol (no cleavage).